Annatto Powder (Bixa orellana) organic

SAFETY DATA SHEETS

According to the UN GHS revision 8

Version: 1.0

Creation Date: July 15, 2019

Revision Date: July 15, 2019

SECTION 1: Identification

1.1

GHS Product identifier

Product name

Annatto

1.2

Other means of identification

Product number	-
Other names	-

1.3

Recommended use of the chemical and restrictions on use

Recommended Usage:	Ingredients for cosmetics, soaps, bath products, watercolour, fabrics and other colouring projects.
Uses advised against	no data available

1.4

Supplier's details

Company	DekelDyes Natural Dye Supplies
Address	Emek Ayalon 14A Shoham _Israel
Telephone	972525410033

1.5

Emergency phone number

Emergency phone number	972525410033
Service hours	24/7

SECTION 2: Hazard identification

2.1

Classification of the substance or mixture

Skin irritation, Category 2

Eye irritation, Category 2

2.2

GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Warning
Hazard statement(s)	H315 Causes skin irritation H319 Causes serious eye irritation
Precautionary statement(s)
Prevention	P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
Response	P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P317 If skin irritation occurs: Get medical help. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage	none
Disposal	none

2.3

Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients

3.1

Substances

Chemical name	Common names and synonyms	CAS number	EC number	Concentration
Annatto	Annatto	1393-63-1	215-735-4	100%

SECTION 4: First-aid measures

4.1

Description of necessary first-aid measures

If inhaled

Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

Following skin contact

Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

Following eye contact

Rinse with pure water for at least 15 minutes. Consult a doctor.

Following ingestion

Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.

4.2

Most important symptoms/effects, acute and delayed

no data available

4.3

Indication of immediate medical attention and special treatment needed, if necessary

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Poisons A and B

SECTION 5: Fire-fighting measures

5.1

Suitable extinguishing media

Use dry chemical, carbon dioxide or alcohol-resistant foam.

5.2

Specific hazards arising from the chemical

no data available

5.3

Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6: Accidental release measures

6.1

Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.

6.2

Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.

6.3

Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

SECTION 7: Handling and storage

7.1

Precautions for safe handling

Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

7.2

Conditions for safe storage, including any incompatibilities

Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

SECTION 8: Exposure controls/personal protection

8.1

Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2

Appropriate engineering controls

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

8.3

Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).

Skin protection

Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state	no data available
Colour	Yellow-red solutions or powder /Extract/
Odour	no data available
Melting point/freezing point	no data available
Boiling point or initial boiling point and boiling range	640.4ºC at 760mmHg
Flammability	no data available
Lower and upper explosion limit/flammability limit	no data available
Flash point	355.1ºC
Auto-ignition temperature	no data available
Decomposition temperature	no data available
pH	no data available
Kinematic viscosity	no data available
Solubility	Soluble in alcohol, ether, oils
Partition coefficient n-octanol/water	log Kow = 7.36 (estimated)
Vapour pressure	4.79E-18mmHg at 25°C
Density and/or relative density	1.069g/cm3
Relative vapour density	no data available
Particle characteristics	no data available

SECTION 10: Stability and reactivity

10.1    Reactivity             no data available

10.2    Chemical stability         no data available

10.3    Possibility of hazardous reactions    no data available

10.4    Conditions to avoid        no data available

10.5    Incompatible materials        no data available

10.6    Hazardous decomposition products    When heated to decomposition it emit acrid smoke and                                 irritating fume.

SECTION 11: Toxicological information

Acute toxicity

• Oral: LD50 Rat oral >50 mL Fat soluble Annatto
• Inhalation: no data available
• Dermal: no data available

Skin corrosion/irritation        no data available

Serious eye damage/irritation    no data available

Respiratory or skin sensitization    no data available

Germ cell mutagenicity        no data available

Carcinogenicity            no data available

Reproductive toxicity        no data available

STOT-single exposure        no data available

STOT-repeated exposure    no data available

Aspiration hazard        no data available

SECTION 12: Ecological information

12.1    Toxicity

• Toxicity to fish: no data available
• Toxicity to daphnia and other aquatic invertebrates: no data available
• Toxicity to algae: no data available
• Toxicity to microorganisms: no data available

12.2

Persistence and degradability

no data available

12.3

Bioaccumulative potential

An estimated BCF of 56 was calculated in fish for annatto(SRC), using an estimated log Kow of 7.4(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is moderate(SRC), provided the compound is not metabolized by the organism(SRC).

12.4

Mobility in soil

Using a structure estimation method based on molecular connectivity indices(1), the Koc of annatto can be estimated to be 7.2X10+5(SRC). According to a classification scheme(2), this estimated Koc value suggests that annatto is expected to be immobile in soil.

12.5

Other adverse effects

no data available

SECTION 13: Disposal considerations

13.1

Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information

14.1

UN Number

ADR/RID: no data available

IMDG: no data available

IATA: no data available

14.2

UN Proper Shipping Name

ADR/RID: no data available

IMDG: no data available

IATA: no data available

14.3

Transport hazard class(es)

ADR/RID: no data available

IMDG: no data available

IATA: no data available

14.4

Packing group, if applicable

ADR/RID: no data available

IMDG: no data available

IATA: no data available

14.5

Environmental hazards

ADR/RID: No

IMDG: No

IATA: No

14.6

Special precautions for user

no data available

14.7

Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information

15.1

Safety, health and environmental regulations specific for the product in question

Chemical name	Common names and synonyms	CAS number	EC number
Annatto	Annatto	1393-63-1	215-735-4
European Inventory of Existing Commercial Chemical Substances (EINECS)	Listed.
EC Inventory	Listed.
United States Toxic Substances Control Act (TSCA) Inventory	Listed.
China Catalog of Hazardous chemicals 2015	Not Listed.
New Zealand Inventory of Chemicals (NZIoC)	Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS)	Listed.
Vietnam National Chemical Inventory	Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)	Listed.
Korea Existing Chemicals List (KECL)	Not Listed.

SECTION 16: Other information

Information on revision

Creation Date	July 15, 2019
Revision Date	July 15, 2019

Abbreviations and acronyms

• CAS: Chemical Abstracts Service
• ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
• RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
• IMDG: International Maritime Dangerous Goods
• IATA: International Air Transportation Association
• TWA: Time Weighted Average
• STEL: Short term exposure limit
• LC50: Lethal Concentration 50%
• LD50: Lethal Dose 50%
• EC50: Effective Concentration 50%

References

• IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
• HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
• IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
• eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
• CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
• ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
• ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
• Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
• ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Any questions regarding this SDS, Please send your inquiry to suzannedekel@gmail.com

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.